Molten Chocolate Cake With Peanut Butter Filling

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1 stick plus 1 tablespoon unsalted butter, plus melted butter for brushing

1 tablespoon unsweetened cocoa powder

1/4 cup plus 1 tablespoon all-purpose flour

6 ounces dark chocolate (70 percent cacao), chopped

3 tablespoons creamy peanut butter

1 tablespoon confectioners' sugar, plus more for sprinkling

1/2 cup granulated sugar

3 large eggs, at room temperature

Pinch of salt

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