Peanut Butter Kahlua Brownies

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1/3 cup Dutch-process cocoa powder

2 teaspoons espresso powder

3/4 cup Kahlua (or other coffee liqueur)

2 ounces unsweetened chocolate, chopped

4 tablespoons unsalted butter, melted

1/2 cup vegetable oil

1 cup peanut butter, divided

2 large eggs

2 large egg yolks

2 teaspoons vanilla extract

2 cups granulated sugar

1 3/4 cups all-purpose flour

3/4 teaspoon salt

6 ounces semisweet chocolate, chopped

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