Double Chocolate Brownies

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6 tablespoons unsalted butter, plus more for pan

6 ounces semisweet chocolate, coarsely chopped

1/4 cup unsweetened Dutch-process cocoa powder

3/4 cup all-purpose flour

1/4 teaspoon baking powder

1/4 teaspoon coarse salt

1 cup sugar

2 large eggs

2 teaspoons pure vanilla extract

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