Chocolate Raspberry Upside-Down Cakes

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2 oz semisweet chocolate, chopped (or 1/3 cup chocolate chips)

1/4 cup butter, softened, plus more for buttering dishes

2/3 cup brown sugar, plus 6 teaspoons

3 cups frozen raspberries

2 egg yolks

1/2 tsp vanilla extract

2/3 cup flour

1/2 cup unsweetened cocoa powder

1/4 tsp baking soda

1/4 tsp salt

2/3 cup buttermilk

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