Chocolate Peanut Butter Cake With Bittersweet Ganache

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Cooking spray

1 tablespoon cake flour

1/2 cup unsweetened cocoa

1/2 cup boiling water

1 (1-ounce) square bittersweet chocolate

3/4 cup granulated sugar

1/2 cup packed dark brown sugar

1/4 cup butter, softened

1/2 cup egg substitute

2 cups cake flour (about 8 ounces)

1 1/2 teaspoons baking soda

1/4 teaspoon salt

1 cup fat-free buttermilk

1/3 cup fat-free sour cream

2 teaspoons vanilla extract

3/4 cup peanut butter and milk chocolate chips

2 cups frozen reduced-calorie whipped topping, thawed

2/3 cup granulated sugar

1/3 cup evaporated fat-free milk

1 tablespoon butter

1/8 teaspoon salt

2 (1-ounce) squares bittersweet chocolate, chopped

1 teaspoon vanilla extract

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