Mexican Hot Chocolate Cupcakes

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1 cup flour

1 cup granulated sugar, divided

6 tbsp unsweetened cocoa powder, divided

2 tsp baking powder

2 tsp ancho chile pepper

1 tsp ground cinnamon

1/4 tsp salt

1/2 cup milk

1/4 cup vegetable oil

1 tsp pure vanilla extract

1 cup boiling water

3/4 cup heavy cream

2 tbsp confectioners sugar

1 tbsp unsweetened cocoa powder

1/2 tsp vanilla extract

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