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Chocolate Coffee Cake

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¾ cup unsweetened cocoa powder

2/3 cup sour cream

2 2/3 cups flour

2 tsp. baking powder

1 tsp. baking soda

½ tsp. salt

¾ cup (1½ sticks) unsalted butter, softened

½ cup vegetable shortening

1½ cups granulated sugar

1 cup firmly packed dark brown sugar

3 large eggs, at room temperature

1 tbsp. vanilla extract

1/3 cup flour

1½ cups whole milk

1/3 cup heavy cream

1½ cups (3 sticks) unsalted butter, softened, cut into small pieces

1 tsp. vanilla extract

3 tbsp. coffee extract

8 ounces good-quality (60 to 72%) dark chocolate, coarsely chopped

¾ cup (1½ sticks) unsalted butter, softened, cut into pieces

1 tbsp. light corn syrup

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