Fennel-Brined Pork Chops

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3 1/2 cups water, divided

1/2 cup chopped fennel fronds

1 tablespoon fennel seeds

1/4 cup kosher salt (such as Diamond Crystal)

1/4 cup sugar

2 tablespoons sambuca or other anise-flavored liqueur

1 cup ice cubes

4 (4-ounce) boneless center-cut loin pork chops (about 3/4 inch thick)

Cooking spray

2 teaspoons chopped fresh rosemary

1 teaspoon freshly ground black pepper

2 garlic cloves, minced

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