Devil's Food Cupcakes With Espresso Meringue

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Vegetable oil spray

4 ounces unsweetened chocolate, finely chopped

1/4 cup Dutch-process cocoa powder, plus more for sprinkling

1 1/4 cups boiling water

1 1/2 cups all-purpose flour

1 teaspoon baking soda

1/4 teaspoon salt

2 sticks unsalted butter (1/2 pound), softened

1 1/2 cups packed dark brown sugar

3 large eggs

1/2 cup buttermilk

1 teaspoon pure vanilla extract

3 large egg whites

1 1/2 cups confectioners' sugar

1 teaspoon instant espresso, plus more for sprinkling

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