Smoked Prime Rib With Peach-Chipotle Sauce

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1 cup light brown sugar

¾ cup chunky peach preserves

½ cup ketchup

¼ chili sauce, such as Heinz

¼ cup apple cider vinegar

¼ cup Worcestershire sauce

¼ cup plus 1 tsp. kosher salt

2 tbsp. molasses

2 tbsp. rice vinegar

½ tsp. chipotle chile powder

1 (28-oz.) can whole, peeled tomatoes, crushed by hand

¼ cup ground black pepper

2 tsp. cayenne

1 (7-rib) prime rib roast (about 16–18 1b.), untrimmed

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