Old-Fashioned Chocolate Layer Cake

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12 Tablespoons (1 1/2 sticks) unsalted butter, very soft, plus extra for greasing pans

1 3/4 cups all-purpose flour, plus extra for dusting pans

4 oz unsweetened chocolate, coarsley chopped

1/4 cup dutch-processed cocoa powder

1/2 cup hot water

1 3/4 C sugar

1 1/2 teaspoons baking soda

1 teaspoon table salt

1 cup buttermilk

2 teaspoons vanilla extract

4 large eggs, plus 2 large egg yolks

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