Chianti Chocolate Cupcakes

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1/4 cup unsweetened cocoa powder

2 oz. dark chocolate (72%) broken into small pieces

1/4 cup boiling water

1 stick (8 oz.) butter, softened

3/4 cup granulated sugar

2 large eggs

1/2 cup plus 1/8 cup all purpose flour

3/4 tsp baking powder

1/8 tsp baking soda

1/2 tsp salt

1/4 cup Chianti red wine

1 cup Chianti wine plus 4 tablespoons, divided

1/4 cup granulated sugar

2 sticks of butter, softened (not room temperature, butter should still be a little cold)

3 cups confectioners' sugar

1/4 tsp salt

Small seedless red grapes for garnish

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