Flank Steak With Five-Spice Rub And Chile Relish

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2 poblano chiles

1 orange bell pepper

1 1/2 tablespoons chopped dry-roasted peanuts

1 tablespoon chopped fresh cilantro

1 tablespoon seasoned rice vinegar

1/4 teaspoon kosher salt

1/4 teaspoon freshly ground black pepper

1 garlic clove, minced

1 tablespoon brown sugar

2 teaspoons kosher salt

1 teaspoon ground cumin

1/2 teaspoon five-spice powder

1/4 teaspoon ground ginger

1 (2-pound) flank steak, trimmed

Cooking spray

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