Carmelized Apple Upside-Down Spice Cake

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6 tablespoons unsalted butter

5 Fuji or Granny Smith apples (about 2 1/2 pounds)—peeled, cored and cut into 6 wedges each

1/4 cup brandy

1 cup sugar

1/2 cup plus 2 tablespoons buttermilk

3 large egg yolks

1 teaspoon pure vanilla extract

1 cup cake flour

3/4 cup sugar

1/2 cup all-purpose flour

1 3/4 teaspoons baking powder

1/2 teaspoon baking soda

1/2 teaspoon freshly grated nutmeg

1/2 teaspoon ground cinnamon

1/2 teaspoon ground cloves

1/4 teaspoon salt

6 tablespoons unsalted butter, softened

Vanilla ice cream, for serving

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