Glazed Pear Upside-Down Cake

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6 tablespoons butter, divided

1/4 cup light brown sugar

2 large pears (8 oz. each), peeled, quartered and cored

1-1/8 cup all-purpose flour

3/4 teaspoon baking powder

3/4 teaspoon baking soda

1/2 teaspoon cinnamon

1/2 teaspoon nutmeg

1/4 teaspoon ginger

1/4 teaspoon salt

1/8 teaspoon allspice

1/2 cup sugar

1 large egg

1/3 cup buttermilk

1/2 teaspoon vanilla extract

2 tablespoons molasses

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