Chocolate Buttermilk Layer Cake With Chocolate Pudding Frosting

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2 cups cake flour (not self-rising)

1/2 cup unsweetened cocoa powder (not Dutch process)

1/2 teaspoon baking soda

2 teaspoons double-acting baking powder

1 teaspoon salt

1 3/4 cups sugar

1/2 stick (1/4 cup) unsalted butter, softened

3 large eggs

1 teaspoon vanilla extract

1 cup buttermilk

1 cup sugar

3 1/2 tablespoons cornstarch

2 ounces unsweetened chocolate, chopped fine

1 cup boiling water

1 tablespoon orange-flavored liqueur

2 tablespoons unsalted butter, cut into pieces and softened

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