Triple Chocolate Espresso Cookies

By Food52
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12 ounces semi-sweet chocolate chunks or chips, divided

1/2 cup (1 stick) unsalted butter

1 1/2 cup unbleached all purpose flour

1/2 cup natural (non-alkalized) cocoa powder

1/2 teaspoon baking soda

1/4 teaspoon baking powder

1/4 teaspoon kosher or sea salt

2 large eggs, at room temperature

2/3 cups granulated sugar

1/2 cup dark brown sugar, tightly packed

1 tablespoon (or less, to taste) instant espresso powder (recommended: Medaglia d

1 teaspoon pure vanilla extract

1 tablespoon dark rum (optional)

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